242306

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242306

Aldrich

 

Allyl chloroformate

97%

CAS Number:2937-50-0
Linear Formula:ClCOOCH2CH=CH2
Molecular Weight:120.53
Beilstein Registry Number:773915
EC Number:220-916-6
MDL number:MFCD00000648
PubChem Substance ID:24854549

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Description

ApplicationReagent employed in ring-expanding allylation leading to 1,4-cycloheptanediones.1
Packaging5, 100 g in glass btl

Properties

vapor pressure3.67 psi ( 20 °C)
assay97%
refractive indexn20/D 1.422(lit.)
bp~27 °C/11 mmHg(lit.)
density1.134 g/mL at 20 °C(lit.)

Safety

Hazard CodesT+
Risk Statements10-22-26-34
Safety Statements26-28-36/37/39-45
RIDADRUN 1722 6.1/PG 1
WGK Germany3
RTECSLQ5775000
Flash Point(F)88 °F
Flash Point(C)31 °C

References

Cited Reference1. Angew. Chem. Int. Ed. Engl. 46, 3966, (2007) Abstract
BeilsteinBeil. 3,IV,29
FieserFieser 12,15 / Fieser 13,9
referenceAldrich MSDS 1, 43:A / Corp MSDS 1 (1), 98:A / FT-IR 2 (1), 1240:D / FT-IR 1 (1), 737:A / FT-NMR 1 (1), 1206:B / NMR-Reference 2 (1), 621:C / RegBook 1 (1), 863:B / Sax 6, 163 / Structure Index 1, 132:D:7